{"organism":"Page","children":[{"organism":"Container.Raw","children":[{"organism":"Metadata","model":{"title":"Solve adhesion failures with the right polyols for adhesives","text":"\u003Cp\u003EDiscover how polyether polyols can help overcome the impact of adhesive temperature, moisture, and UV rays for packaging, footwear, construction and automotive. \u003C/p\u003E\r\n\r\n\r\n\r\n\r\n","links":[{"name":"Solve adhesion failures with the right polyols for adhesives","value":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives.html"}],"image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/metadata.shellimg.png/1756986430164/caulking-gun-applying-adhesive-to-a-surface.png","alt":"caulking gun applying adhesive to a surface","width":3840,"height":2166}},"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/metadata"},{"organism":"ContentOwner","model":{},"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/contentowner"},{"organism":"Container.Header","children":[{"organism":"Container.Raw","ref":"https://www.shell.com/_jcr_content/root/header/inherited.model.json","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/header/inherited","model":{}},{"organism":"Breadcrumb","model":{"links":[{"name":"Home","value":"https://www.shell.com/"},{"name":"Business customers","value":"https://www.shell.com/business-customers.html"},{"name":"Shell Chemicals","value":"https://www.shell.com/business-customers/chemicals.html"},{"name":"Resources & Insights","value":"https://www.shell.com/business-customers/chemicals/resources.html"},{"name":"Solve adhesion failures with the right polyols for adhesives","value":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives.html"}]},"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/header/breadcrumb"}],"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/header","model":{}},{"organism":"Container.Main","children":[{"organism":"Container.Section","children":[{"organism":"PageHeader","color":"semitransparent","model":{"title":"Solve adhesion failures with the right polyols for adhesives","image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/main/section/page_header.shellimg.png/1765395066114/caulking-gun-applying-adhesive-to-a-surface.png","alt":"caulking gun applying adhesive to a surface","width":3840,"height":903}},"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/page_header"},{"organism":"PromoFull","color":"brand3-solid","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/promo_copy","model":{"title":" From automotive to construction, poor adhesion shortens product lifespans and compromises structural integrity, safety, and reputation.","text":"\u003Cp\u003EEnvironmental stressors, including moisture, UV rays, and extreme temperatures, are tied to adhesive failures, prompting manufacturers to re-evaluate formulations for longevity.\u003C/p\u003E\r\n\u003Cp\u003EThe difference between adhesion that fails or endures often lies in one critical formulation building block: polyols.\u003C/p\u003E\r\n\u003Cp\u003EExplore how strategically selecting polyols for adhesives can elevate performance in today’s most demanding applications.\u003C/p\u003E\r\n","image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/main/section/promo_copy.shellimg.png/1765397790240/person-spreading-adhesive-on-a-floor-surface-for-tile-installation.png","alt":"person spreading adhesive on a floor surface for tile installation","width":3840,"height":2160}}},{"organism":"PromoSimple.Text","color":"brand4-solid","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text","model":{"title":"Why moisture still wrecks adhesive performance","text":"\u003Cp\u003EWithout a proper moisture barrier, adhesives can lose strength, suffer from hydrolysis, and ultimately fail at the joint.\u003Csup\u003E1\u003C/sup\u003E Moisture intrusion remains a leading cause of adhesive degradation across industries, but the consequences vary by application.\u003C/p\u003E\r\n\u003Cp\u003E\u003Cstrong\u003EMoisture impact by sector\u003C/strong\u003E\u003C/p\u003E\r\n\u003Cul\u003E\u003Cli\u003EPackaging - Causes delamination and shortens packaging life, compromising product safety. \u003Csup\u003E2 3\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EFootwear - Exposure to rain, water, or sweat can cause adhesives to peel. \u003Csup\u003E4\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EConstruction - Moisture exposure undermines the structural integrity of construction-based adhesives. \u003Csup\u003E5\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EAutomotive - Accelerates degradation of adhesive bonds, impacting performance and durability. \u003Csup\u003E6\u003C/sup\u003E\u003C/li\u003E\u003C/ul\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"brand1-subtle","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_1274461132_copy","model":{"title":"How polyols help mitigate moisture challenges","text":"\u003Cp\u003EDue to their hydrophobic nature, polyether polyols, like Shell CARADOL\u003Csup\u003E®\u003C/sup\u003E, offer superior moisture resistance. They repel water rather than absorb it, making them ideal for indoor and outdoor applications where adhesives must perform under variable conditions. \u003Csup\u003E7 8 9\u003C/sup\u003E\u003C/p\u003E\r\n\u003Cp\u003EPolyether polyols are less prone to hydrolysis, making them a strategic building block in formulas for moist environments. \u003Csup\u003E10\u003C/sup\u003E\u003C/p\u003E\r\n\u003Cp\u003E\u003Cb\u003ELooking to explore more strategies for high-performance adhesion? Download \u003Ca href=\"https://cloud.chemical.shell.com/making-it-stick\" target=\"_blank\" rel=\"noopener noreferrer\"\u003EMaking it Stick\u003C/a\u003E.\u003C/b\u003E\u003C/p\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"brand5-solid","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_copy","model":{"title":"How UV exposure compromises adhesives","text":"\u003Cp\u003EWithout UV-resistance, adhesives are prone to discolouration and physical degradation, compromising product quality and lifespan. UV exposure affects adhesives differently depending on the application.\u003C/p\u003E\r\n\u003Cp\u003E\u003Cstrong\u003EUV impact by sector\u003C/strong\u003E\u003C/p\u003E\r\n\u003Cul\u003E\u003Cli\u003EPackaging - Causes discolouration and reduces joint strength, impacting shelf appeal. \u003Csup\u003E11\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EFootwear - Creates adverse cosmetic effects and physical alterations, affecting product durability. \u003Csup\u003E12\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EConstruction - Photodegradation breaks polymer bonds, leading to property loss and discolouration. \u003Csup\u003E13\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EAutomotive - Prolonged exposure creates cracking and discolouration. \u003Csup\u003E14\u003C/sup\u003E\u003C/li\u003E\u003C/ul\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"brand1-subtle","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_1274461132_copy_575762388","model":{"title":"How stabilisers help mitigate UV challenges","text":"\u003Cp\u003EPolyether polyols can be formulated with UV stabilisers to counteract discolouration. \u003Csup\u003E15\u003C/sup\u003E While inherently sensitive to UV radiation, polyether-based adhesives for outdoor use often include stabilisers and fillers to block or absorb harmful rays.\u003C/p\u003E\r\n\u003Cp\u003EAdditionally, polyether polyols offer greater flexibility, helping maintain bond integrity and can reduce cracking from prolonged UV exposure. \u003Csup\u003E16\u003C/sup\u003E\u003C/p\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"brand1-solid","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_copy_1348351799","model":{"title":"How polyols improve adhesive temperature performance","text":"\u003Cp\u003EExtreme heat or cold can impact adhesive durability and reliability without strategic polyol selection. Temperature affects adhesives differently across industries.\u003C/p\u003E\r\n\u003Cp\u003E\u003Cstrong\u003ETemperature impact by sector\u003C/strong\u003E\u003C/p\u003E\r\n\u003Cul\u003E\u003Cli\u003EPackaging High heat can soften bonds, while cold can cause brittleness. \u003Csup\u003E17\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EFootwear Adhesives soften in high temperatures and lose flexibility in cold, leading to cracking.\u003Csup\u003E 18\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EConstruction Exposure to extreme temperatures can degrade adhesives in flooring and structural use. \u003Csup\u003E19\u003C/sup\u003E\u003C/li\u003E\u003Cli\u003EAutomotive Thermal expansion and contraction reduce bond strength, risking failure. \u003Csup\u003E20\u003C/sup\u003E\u003C/li\u003E\u003C/ul\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"brand1-subtle","colspan":6,"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_1274461132_copy_1234344514","model":{"title":"How polyols help mitigate temperature challenges","text":"\u003Cp\u003EPolyether polyols offer improved flexibility and excellent low and high-temperature performance. \u003Csup\u003E21 22 23\u003C/sup\u003E Their cold-weather resilience can prevent brittleness, while their high-heat resistance supports durability. \u003Csup\u003E24\u003C/sup\u003E\u003C/p\u003E\r\n\u003Cp\u003EDue to their more flexible ether bonds, polyether polyols can enable better performance in cold environments.\u003Csup\u003E25\u003C/sup\u003E This makes them ideal for adhesives used in outdoor and all-weather applications.\u003C/p\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"inherited","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_1403077222","model":{"title":"Common bond failures formulators face","text":"\u003Cp\u003EIn addition to environmental stressors, formulators often face three core bond failure types: adhesive, cohesion, and substrate failure. Each presents unique challenges that polyol selection can help address.\u003C/p\u003E\r\n"}},{"organism":"PromoSimple.Text","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section/text_1629754420","model":{"text":"\u003Ctable cellpadding=\"1\" cellspacing=\"0\" border=\"1\"\u003E\n\u003Ctbody\u003E\u003Ctr\u003E\u003Ctd\u003E\u003Cb\u003EFailure type\u003C/b\u003E\u003C/td\u003E\n\u003Ctd\u003E\u003Cb\u003EWhat happens\u003C/b\u003E\u003C/td\u003E\n\u003Ctd\u003E\u003Cb\u003ECommon causes\u003C/b\u003E\u003C/td\u003E\n\u003C/tr\u003E\u003Ctr\u003E\u003Ctd\u003EAdhesive \u003C/td\u003E\n\u003Ctd\u003EThe adhesive fails to bond to one or both surfaces.\u003C/td\u003E\n\u003Ctd\u003EPoor surface preparation, low application temperature, insufficient wetting, or incompatibility.\u003C/td\u003E\n\u003C/tr\u003E\u003Ctr\u003E\u003Ctd\u003ECohesion\u003C/td\u003E\n\u003Ctd\u003EThe adhesive splits within itself, not at the substrate.\u003C/td\u003E\n\u003Ctd\u003EInadequate curing, contamination, or improper preparation.\u003C/td\u003E\n\u003C/tr\u003E\u003Ctr\u003E\u003Ctd\u003ESubstrate\u003C/td\u003E\n\u003Ctd\u003EThe bonded material itself breaks.\u003C/td\u003E\n\u003Ctd\u003EThe adhesive bond is stronger than the substrate, a desired result unless debonding is needed.\u003C/td\u003E\n\u003C/tr\u003E\u003C/tbody\u003E\u003C/table\u003E\n"}}],"id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section","model":{}},{"organism":"Container.Section","color":"inherited","children":[{"organism":"StandaloneAsset","color":"inherited","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section_561699083/standalone_asset","model":{"image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/main/section_561699083/standalone_asset.shellimg.png/1756986384131/diagram-showing-three-types-of-adhesive-bond-failures.png","alt":"Diagram showing three types of adhesive bond failures","width":3840,"height":2001}}},{"organism":"PromoFull","color":"brand3-solid","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section_561699083/promo_copy_copy","model":{"title":" How polyols help mitigate failures","text":"\u003Cp\u003EPolyether polyols offer lower viscosity and have better wetting characteristics, improving surface adhesion. This can help reduce the likelihood of adhesive failure, especially on complex surfaces.\u003C/p\u003E\r\n\r\n\u003Cp\u003EAdditionally, polyether-based polyurethane (PU) adhesives are often easier to process, which can help formulators achieve more consistent application, better cure profiles, and stronger overall bond integrity.\u003C/p\u003E\r\n\r\n\r\n","image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/main/section_561699083/promo_copy_copy.shellimg.png/1756986361360/applying-adhesive-to-surface.png","alt":"applying adhesive to surface","width":3840,"height":2160}}},{"organism":"PromoFull.Right","color":"brand1-subtle","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section_561699083/promo_copy_copy_1553","model":{"title":" Strengthen performance with polyether polyols for adhesives","text":"\u003Cp\u003EAdhesive manufacturers can overcome common environmental and bonding challenges by selecting the right polyol for the formulation.\u003C/p\u003E\n\u003Cp\u003EPolyether polyols can help enhance performance in critical areas, including:\u003C/p\u003E\n\u003Cul\u003E\n\u003Cli\u003E Water resistance\u003C/li\u003E\n\u003Cli\u003E UV stability\u003C/li\u003E\n\u003Cli\u003ETemperature durability (hot and cold)\u003C/li\u003E\n\u003Cli\u003EAdhesion strength\u003C/li\u003E\n\u003Cli\u003EBond reliability\u003C/li\u003E\n\u003C/ul\u003E\n\u003Cp\u003EEnvironmental stressors and bond failures don’t have to limit adhesive performance. With Shell CARADOL polyether polyols, manufacturers can develop adhesives that last across industries, climates, and materials.\u003C/p\u003E\n\u003Cp\u003E\u003Ca href=\"https://www.shell.com/business-customers/chemicals/our-products/polyols/case-polyols-product-brochure.html\"\u003EExplore our brochure\u003C/a\u003E to discover polyol solutions tailored to your application, or \u003Ca href=\"https://www.shell.com/business-customers/chemicals/digital-portal/connect-with-shell-chemicals.html\"\u003Espeak to an expert\u003C/a\u003E to find the right Shell CARADOL polyol for your formulation needs.\u003C/p\u003E\n","image":{"src":"https://www.shell.com/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/_jcr_content/root/main/section_561699083/promo_copy_copy_1553.shellimg.png/1765396316002/person-applying-adhesive-onto-a-large-industrial-surface.png","alt":"person applying adhesive onto a large industrial surface","width":3171,"height":2160}}},{"organism":"PromoSimple.Text","color":"inherited","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section_561699083/text","model":{"title":"Related Resources","text":"\u003Cul\u003E\r\n\u003Cli\u003E\u003Ca href=\"https://www.shell.com/business-customers/chemicals/resources/propel-polyurethane-footwear-formulas-forward.html\"\u003EHow to propel polyurethane footwear formulas forward\u003C/a\u003E\u003C/li\u003E\r\n\u003Cli\u003E\u003Ca href=\"https://www.shell.com/business-customers/chemicals/resources/missing-the-mark-on-comfort.html\"\u003EDriving comfort and durability: How polyether polyols are shaping the cars of tomorrow\u003C/a\u003E\u003C/li\u003E\r\n\u003C/ul\u003E\r\n"}},{"organism":"PromoSimple.Text","color":"inherited","id":"/content/shell/corporate/global/en_gb/business-customers/chemicals/resources/solve-adhesion-failures-with-the-right-polyols-for-adhesives/jcr_content/root/main/section_561699083/text_264156863","model":{"title":"Sources","text":"\u003Cp\u003E\u003Csup\u003E1\u003C/sup\u003E https://adhesives.specialchem.com/tech-library/article/improving-the-moisture-resistance-of-adhesives-and-sealants-part-ii\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E2\u003C/sup\u003E https://link.springer.com/chapter/10.1007/0-387-32989-7_37\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E3\u003C/sup\u003E https://adhesives.org/markets/paperboard-packaging/\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E4\u003C/sup\u003E https://journals.sagepub.com/doi/10.1177/1464420715602441?icid=int.sj-full-text.similar-articles.1\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E5\u003C/sup\u003E https://adhesives.org/markets/building-construction/\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E6\u003C/sup\u003E https://www.sciencegate.app/document/10.1177/0954406220944208\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E7\u003C/sup\u003E https://pubs.acs.org/doi/pdf/10.1021/bk-2021-1399.ch001\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E8\u003C/sup\u003E https://adhesives.specialchem.com/tech-library/article/improving-the-moisture-resistance-of-adhesives-and-sealants-part-ii\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E9\u003C/sup\u003E https://www.sciencedirect.com/science/article/abs/pii/S0079670018302995\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E10\u003C/sup\u003E https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.1c02558\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E11\u003C/sup\u003E https://adhesives.specialchem.com/selection-guide/uv-light-stabilizers-state-of-the-art\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E12\u003C/sup\u003E https://adhesives.specialchem.com/selection-guide/uv-light-stabilizers-state-of-the-art\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E13\u003C/sup\u003E https://adhesives.specialchem.com/selection-guide/uv-light-stabilizers-state-of-the-art\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E14\u003C/sup\u003E https://adhesives.specialchem.com/selection-guide/uv-light-stabilizers-state-of-the-art\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E15\u003C/sup\u003E https://pmc.ncbi.nlm.nih.gov/articles/PMC11085269/\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E16\u003C/sup\u003E https://www.sciencedirect.com/science/article/pii/S2542504820300269\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E17\u003C/sup\u003E https://www.sciencedirect.com/science/article/abs/pii/S1359836818316184\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E18\u003C/sup\u003E https://www.sciencedirect.com/science/article/abs/pii/S1359836818316184\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E19\u003C/sup\u003E https://adhesives.org/markets/building-construction/\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E20\u003C/sup\u003E https://www.researchgate.net/profile/M-Banea/publication/245389867_The_effect_of_temperature_on_the_mechanical_properties_of_adhesives_for_the_automotive_industry/links/54983df90cf2519f5a1dda97/The-effect-of-temperature-on-the-mechanical-properties-of-adhesives-for-the-automotive-industry.pdf\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E21\u003C/sup\u003E https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.1c02558\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E22\u003C/sup\u003E https://www.google.com/books/edition/Handbook_on_Modern_Packaging_Industries/3i8XDAAAQBAJ?hl=en&gbpv=1&dq=polyether+polyols+high+and+low+%22temperature%22+resistance,+cold+and+heat&pg=PA12&printsec=frontcover\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E23\u003C/sup\u003E https://link.springer.com/article/10.1007/s13233-020-8138-5\u003C/p\u003E\n\u003Cp\u003E\u003Csup\u003E24\u003C/sup\u003E 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